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Chiral metallic complexes used in asymmetric synthesis were reviewed in this paper.Particular emphasis is placed on the asymmetric epoxidation and asymmetric hydrogenation,etc. 综述金属有机配合物在不对称合成中的应用,即金属有机催化剂在不对称催化氢化、不对称环氧化、不对称环丙烷化等反应中的应用以及最新的进展。
This review involves chiral metal complexes as catalysts for asymmetric epoxidation of simple olfins. 介绍了多类简单烯烃不对称环氧化反应的手性过渡金属配合物催化剂系统的催化效果。
The most efficient way to generate chiral sulfoxides is asymmetric oxidation of prochiral sulfides Catalyzed by chiral metal complexes. 摘要手性金属络合物催化硫醚的不对称氧化是合成手性亚砜最有效的方法。
Chiral Metallic Complexes Used in Asymmetric Synthesis 金属有机配合物在不对称合成中的应用
chiral metallic complexes 不对称催化
Keywords Molecular mechanics;MM2;Molecular dynamics simulation;Chiral metal complex; 分子力学;MM2力场分子动力学模拟;手性金属配合物;
Application of the asymmetric hydrosilation and alkylation using chiral metal coordinate complexes as catalysts are discussed. 本文论述了手性金属络合物催化剂在不对称硅氢化反应及其在二烷基锌对醛的不对称烷基化反应中的应用。
chiral metal complex 手性金属配合物
The synthesis and applications in catalytic asymmetric synthesis of C2-symmetric chiral bis (oxazoline) and its metal complexes are reviewed in this article. 摘要本文综述了手性双恶唑啉的合成及其金属配合物作为手性催化剂在催化不对称反应中的应用研究进展。
Chiral Salen Shiff-base metal complexes can be polymerized, which afford chiral line or net polymeric Salen metal complexes. 线形与平面型聚金属卟啉与金属酞菁表现出良好的导电性与催化活性；
Chiral Salen Shift-base metal complexes can be polymerized, which afford chiral line or net polymeric Salen metal complexes. 线形与平面型聚金属卟啉与金属酞菁表现出良好的导电性与催化活性；
The synthesis and applications in catalytic asymmetric synthesis of C2- symmetric chiral bis( oxazoline) and its metal complexes are reviewed in this article. 本文综述了手性双恶唑啉的合成及其金属配合物作为手性催化剂在催化不对称反应中的应用研究进展。
Based on brief introduction about all kinds of chiral bis-oxazoline ligands,the application of their metal complexes to asymmetric synthesis in recent years was reviewed. 在简要介绍各种结构类型的手性双恶唑啉配体的基础上,总结了近期手性双恶唑啉金属配合物在不对称合成中的应用。
The research advances of the chiral ligands metal complexes catalysts used in asymmetric 1,3-dipolar cycloaddition reactions were reviewed in this paper. 综述了手性配体金属络合物催化剂催化1,3-偶极环加成反应的研究进展。
Recent advances in asymmetric hydrosilylation of prochiral carbonyl compounds catalyzed by chiral transition metal complexes are reviewed in this paper with 47 references. 评述了近年来手性金属配合物催化的前手性羰基化合物的不对称硅氢化反应研究进展。
The applications and recent developments of chiral macromolecular ligand metal complexes in asymmetric catalysis were reviewed.53 references were presented. 综述了手性高分子金属络合物(人工合成)在不对称催化中的应用及最新进展,参考文献53篇。
Abstract: Recent advances in asymmetric hydrosilylation of prochiral carbonyl compounds catalyzed by chiral transition metal complexes are reviewed in this paper with 47 references. 文摘:评述了近年来手性金属配合物催化的前手性羰基化合物的不对称硅氢化反应研究进展。
In this paper, porphyrins and their metallic complexes as organic light-emitting diodes (OLED) are reviewed. 本文对卟啉及其金属配合物在有机电致发光材料方面的研究做了综述。
It is difficult to state when the first metal complex was discovered. 很难说出是什么时候第一次发现金属配合物的。
Modern theoretical concepts as applied to metal complexes are used in this book. 本书采用了能应用于金属配合物的一切近代理论概念。