The recent development in the preparation,characterization,and crystal chemistry and thermal stability of oxo-vanadium phosphates with open framework is covered in this review.

• 孔道结构氧-钒基磷酸盐具有丰富而复杂的结构化学特点及特殊的吸附、离子交换、择形催化,以及非线性光学、电磁学等性能,由此成为微孔材料领域研究的热点之一。