Recent researches on mechanism of hydrocarbon selective oxidations with hydrogen peroxide catalyzed by metalloporphyrins including iron porphyrins and manganese porphyrins are reviewed in this paper.

• 本文综合介绍了近年来采用过氧化氢为氧化剂，金属铁卟啉和锰卟啉模拟酶体系催化烯烃环氧化和烷烃氧化的反应机理。