In this paper an equation of reaction speed determined by the experiment is deduced from the composition of the activated complex form the basic assumption of transition-state theory and the basic porperties of thermodynamic equilibrium.

• 从过渡状态理论的基本假设出发,结合热力学平衡及反应速率控制步骤的基本性质,本文提出通过由实验确定的某化学反应的反应速率方程来推算该反应活化络合物组成的简便可行的方法。