Among the applications discussed are cataly-tic asymmetric Grignard cross-coupling byNi and Pd complexes,catalytie asymmetrichydrosilylation by Pd,Pt and Rh oomplexes,catalytic asymmetric hydrogenation by Rhcomplexes,and so on.

• 讨论了手征性二茂铁烷基胺的不对称锂化反应机理,手征性二茂铁膦的镍、钯配合物催化不对称格氏偶合反应,钯、铂、铑配合物催化不对称硅氢化反应,铑配合物催化不对称氢化反应,钴配合物催化不对称氢迁移反应,钯配合物催化不对称环化反应,等等。