Adamantane was synthesized by the batch reactor system in the presence of hydrogen using endo-tetrahydrodicyclopentadiene(endo-TCD) as reactant,solid super-acid ZrO_2-SO~(2-)_4(SZ) loaded REY,USY,Si-MCM-41molecular sieves as isomerizing catalysts.

• 以桥式四氢双环戊二烯(endo-TCD)为反应物,表面负载固体超强酸ZrO2-SO42-的REY,USY,S i-MCM-41等分子筛为异构化反应催化剂,采用间歇反应方式合成了金刚烷。