A resol type phenolic resin/nano clay composites suitable for use in bonding refractory materials were prepared through in-situ intercalated polymerization using pristine Na-montmorillonite.

• 通过原位插层聚合方法在苯酚与甲醛缩合反应过程中引入层状钠基硅酸盐粘土,得到1种纳米粘土改性酚醛树脂的结合剂。