A Waugh type polyoxometalate H_(12)[MnMo_(9)O_(32)(KO)_(6)] was synthesized and structurally characterized by means of single crystal X-ray diffraction,IR,XRD and TG.

• 合成了具有W augh结构的多金属氧酸盐H12[MnMo9O32(KO)6],用X射线单晶衍射、IR、XRD、热重分析对标题化合物进行了表征。