A Dawson structure heteropoly complex K10Na2H2P2 W16O60. 18H2O was prepared and used to catalyze the synthesis of adipic acid from cyclohexanone, oxidized by 30% hydrogen peroxide without any solvent or phase transfer agent.

• 制备了二缺位Dawson结构杂多盐K10Na2H2P2W16O60·18H2O,在无溶剂、无相转移剂的条件下,以 30%25的H2O2为氧源,催化氧化环己酮合成己二酸。